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• W2016087498 endingPage "832" @default.
• W2016087498 startingPage "827" @default.
• W2016087498 abstract "Complex [3a]2+ has been synthesized, which contains one NiII cyclam-like and one bipyridine fragment (cyclam = 1,4,8,11-tetraazacyclotetradecane). Spectrophotometric and potentiometric titration experiments in aqueous solution demonstrated that in the examined pH range (2−10), the NiII cyclam-like subunit remains square planar, i.e., it does not interact with the bipyridine unit, which is instead allowed to bind external metal centers. In particular, in the presence of 0.5 equiv of CuII, the trinuclear multicomponent coordination compound [CuII(3a)2(H2O)]6+ is the only species existing in solution over a wide pH range. The water molecule bound to the CuII center can be substituted by inorganic anions, forming [CuII(3a)2(anion)]5+ species, and the binding constants of a series of mononegative anions have been determined, demonstrating the effectiveness of [CuII(3a)2(H2O)]6+ as an anion receptor. Voltammetric experiments have shown that the two NiII centers in [CuII(3a)2(H2O)]6+ can be reversibly oxidized to NiIII, a d7 cation which needs further coordination in its axial positions. In the case of the [CuII(3a)2(anion)]5+ species, differential-pulse voltammetry experiments demonstrated that on oxidation of the peripheral NiII centers, the anion bound to the central CuII cation jumps onto one of the peripheral NiIII centers. Thus, the translocation of an anion from the center to the periphery (and vice versa) can be electrochemically switched for the multicomponent coordination compound considered here." @default.
• W2016087498 created "2016-06-24" @default.
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• W2016087498 date "1997-02-01" @default.
• W2016087498 modified "2023-10-17" @default.
• W2016087498 title "Electrochemically Switched Anion Translocation in a Multicomponent Coordination Compound" @default.
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• W2016087498 doi "https://doi.org/10.1021/ic960892x" @default.
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