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• W2016090120 abstract "The chemical state of the active phase (Ni–Mo–S and Ni–W–S) of sulfided NiMo and NiW catalysts during the interaction with NO is investigated by extended X-ray absorption fine structure (EXAFS). The results show that approximately 30 % of the Ni atoms in the active phase are oxidized already at room temperature (RT) upon NO exposure. On the average, the chemical state of the W atoms in sulfided NiW/Al2O3 is hardly changed. Essentially all the Ni atoms in the active Ni–Mo–S phase are oxidized above 150°C. Although the present results indicate that significant structural and chemical changes occur when NO is used as a probe molecule in activated hydrotreating catalysts, NO temperature-programmed desorption (TPD) and NO chemisorption can, nevertheless, provide important insight into the nature of the active phase." @default.
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• W2016090120 date "2000-11-01" @default.
• W2016090120 modified "2023-09-27" @default.
• W2016090120 title "The effect of NO adsorption on the chemical state of promoted hydrotreating catalysts" @default.
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• W2016090120 doi "https://doi.org/10.1016/s1381-1169(00)00304-6" @default.
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