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- W2016098462 abstract "A long path FTIR-based product study was carried out by the visible (λ > 400 nm) photolysis of mixtures containing CF3NO, NO and ethane or propane (in mtorr range) in 700 torr of synthetic air at 297 ± 2 K. Kinetic and spectroscopic evidence has been obtained for the reaction (1), CF3O + RH → CF3OH + R (RH = C2H6 or C3H8). Using the reaction (2), CF3O + NO → CF2O + FNO as the reference reaction, values for the relative rate constants k2/k1 were determined to be 50 ± 15(σ) and 20 ± 5(σ) for C2H6 and C3H8, respectively. These results suggest that the hydrocarbon reactions may provide a significant pathway for the tropospheric degradation of HFCs and HCFCs containing a CF3 group." @default.
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- W2016098462 date "1992-11-20" @default.
- W2016098462 modified "2023-10-17" @default.
- W2016098462 title "Long path ftir spectroscopic study of the reactions of CF<sub>3</sub>O radicals with ethane and propane" @default.
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