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- W2016109061 abstract "Ethylene–norbornene (E–N) copolymerizations were carried out by using β-diketiminato nickel complexes CH{C(CF3)NAr}2NiBr (Ar = 2,6-iPr2C6H3, 1; Ar = 2,6-Me2C6H3, 2) in the presence of methylaluminoxane (MAO). Complex 1 bearing bulky isopropyl ortho substituents showed higher activity than 2 for the E–N copolymerization. The activity of the catalytic systems increased with increasing the feed ratio of norbornene/ethylene (N/E), and gave the E–N copolymers with high norbornene content more than 75 mol%. In the microstructures of copolymers generated with the catalytic systems, norbornene microblocks with a length of two or three norbornene units have been detected. Results have shown that the activity and the content of norbornene in copolymer depend on the N/E feed ratio." @default.
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- W2016109061 date "2011-07-01" @default.
- W2016109061 modified "2023-09-30" @default.
- W2016109061 title "Synthesis and structural characterization of ethylene–norbornene copolymer with high norbornene content catalyzed by β-diketiminato nickel/methylaluminoxane" @default.
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- W2016109061 doi "https://doi.org/10.1016/j.eurpolymj.2011.07.012" @default.
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