Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016111642> ?p ?o ?g. }
Showing items 1 to 78 of
78
with 100 items per page.
- W2016111642 endingPage "1101" @default.
- W2016111642 startingPage "1093" @default.
- W2016111642 abstract "Abstract Investigations were made on the effects of zinc and calcium carboxylates, polyols and other oxygen-containing compounds, nitrogen- and sulphur-containing compounds and of mixtures of zinc calcium carboxylates, zinc carboxylates-complexing agent, calcium carboxylate-complexing agent and of zinc carboxylate-calcium carboxylate-complexing agent upon the rate of dehydrochlorination and crosslinking and on the absorption spectrum of PVC during degradation in vacuum at 180°. The interaction of the stabilizers with 2-chlorobutane (a model for normal units of PVC) was studied at 180°. It was shown that, in the thermal degradation of PVC, zinc carboxylates give synergistic mixtures with compounds having -OH, -SH or -NH groups. In the thermal degradation of PVC in the presence of mixtures of zinc carboxylates with polyols, there are exchanges between chloro-containing groups of PVC and carboxylic groups of salt and alcohol residue. Zinc salts also catalyze the interaction of polyols with double (particularly conjugated double) bonds of degraded PVC. The investigated compounds do not form synergistic mixtures with calcium carboxylates. The triple mixtures of zinc and calcium carboxylates with complexing agents are more effective stabilizers of PVC than the binary mixtures zinc carboxylate-calcium carboxylate and zinc carboxylate-complexing agent. The mechanism of synergistic interaction in PVC stabilization by these mixtures are discussed." @default.
- W2016111642 created "2016-06-24" @default.
- W2016111642 creator A5032300227 @default.
- W2016111642 creator A5038969943 @default.
- W2016111642 creator A5066217642 @default.
- W2016111642 date "1982-01-01" @default.
- W2016111642 modified "2023-09-23" @default.
- W2016111642 title "Mechanism of poly(vinyl chloride) stabilization by mixtures of zinc and calcium carboxylates with various complexing agents" @default.
- W2016111642 cites W1983850294 @default.
- W2016111642 cites W2006669939 @default.
- W2016111642 cites W2008099486 @default.
- W2016111642 cites W2018119176 @default.
- W2016111642 cites W2018621455 @default.
- W2016111642 cites W2033595190 @default.
- W2016111642 cites W2050909576 @default.
- W2016111642 cites W2061298081 @default.
- W2016111642 cites W2073202945 @default.
- W2016111642 cites W2499770308 @default.
- W2016111642 doi "https://doi.org/10.1016/0014-3057(82)90210-5" @default.
- W2016111642 hasPublicationYear "1982" @default.
- W2016111642 type Work @default.
- W2016111642 sameAs 2016111642 @default.
- W2016111642 citedByCount "5" @default.
- W2016111642 crossrefType "journal-article" @default.
- W2016111642 hasAuthorship W2016111642A5032300227 @default.
- W2016111642 hasAuthorship W2016111642A5038969943 @default.
- W2016111642 hasAuthorship W2016111642A5066217642 @default.
- W2016111642 hasConcept C111472728 @default.
- W2016111642 hasConcept C138885662 @default.
- W2016111642 hasConcept C15920480 @default.
- W2016111642 hasConcept C178790620 @default.
- W2016111642 hasConcept C179104552 @default.
- W2016111642 hasConcept C185592680 @default.
- W2016111642 hasConcept C188027245 @default.
- W2016111642 hasConcept C192562407 @default.
- W2016111642 hasConcept C197404232 @default.
- W2016111642 hasConcept C2778695967 @default.
- W2016111642 hasConcept C2781460079 @default.
- W2016111642 hasConcept C519063684 @default.
- W2016111642 hasConcept C521977710 @default.
- W2016111642 hasConcept C535196362 @default.
- W2016111642 hasConcept C89611455 @default.
- W2016111642 hasConceptScore W2016111642C111472728 @default.
- W2016111642 hasConceptScore W2016111642C138885662 @default.
- W2016111642 hasConceptScore W2016111642C15920480 @default.
- W2016111642 hasConceptScore W2016111642C178790620 @default.
- W2016111642 hasConceptScore W2016111642C179104552 @default.
- W2016111642 hasConceptScore W2016111642C185592680 @default.
- W2016111642 hasConceptScore W2016111642C188027245 @default.
- W2016111642 hasConceptScore W2016111642C192562407 @default.
- W2016111642 hasConceptScore W2016111642C197404232 @default.
- W2016111642 hasConceptScore W2016111642C2778695967 @default.
- W2016111642 hasConceptScore W2016111642C2781460079 @default.
- W2016111642 hasConceptScore W2016111642C519063684 @default.
- W2016111642 hasConceptScore W2016111642C521977710 @default.
- W2016111642 hasConceptScore W2016111642C535196362 @default.
- W2016111642 hasConceptScore W2016111642C89611455 @default.
- W2016111642 hasIssue "12" @default.
- W2016111642 hasLocation W20161116421 @default.
- W2016111642 hasOpenAccess W2016111642 @default.
- W2016111642 hasPrimaryLocation W20161116421 @default.
- W2016111642 hasRelatedWork W1794687552 @default.
- W2016111642 hasRelatedWork W1982838468 @default.
- W2016111642 hasRelatedWork W1988596740 @default.
- W2016111642 hasRelatedWork W1990253862 @default.
- W2016111642 hasRelatedWork W2028174473 @default.
- W2016111642 hasRelatedWork W2042296481 @default.
- W2016111642 hasRelatedWork W2052804687 @default.
- W2016111642 hasRelatedWork W2075107952 @default.
- W2016111642 hasRelatedWork W2077374604 @default.
- W2016111642 hasRelatedWork W2325092347 @default.
- W2016111642 hasVolume "18" @default.
- W2016111642 isParatext "false" @default.
- W2016111642 isRetracted "false" @default.
- W2016111642 magId "2016111642" @default.
- W2016111642 workType "article" @default.