Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016116859> ?p ?o ?g. }
Showing items 1 to 96 of
96
with 100 items per page.
- W2016116859 endingPage "277" @default.
- W2016116859 startingPage "270" @default.
- W2016116859 abstract "The nature and location of the active sites for the Beckmann rearrangement present in microporous and mesoporous solids have been investigated by comparing the results obtained for oximes of different molecular size, using in situ infrared spectroscopy. The rearrangement of acetophenone and cyclododecanone oximes into acetanilide and laurolactam, respectively, was studied using siliceous and Al-containing zeolites Beta and MFI and mesoporous MCM-41 as catalysts. The results indicate that Brønsted acid sites as well as strongly hydrogen bonded silanol groups and silanol nests, located in the pores of zeolites and MCM-41, are active in the reaction. When the external surface or the outer shell of MFI type crystals is considered, the bridging hydroxyl groups appear to be active, whereas no activity in the Beckmann rearrangement of cyclododecanone is observed over silanol groups." @default.
- W2016116859 created "2016-06-24" @default.
- W2016116859 creator A5000454699 @default.
- W2016116859 creator A5005652685 @default.
- W2016116859 creator A5011530797 @default.
- W2016116859 creator A5044747959 @default.
- W2016116859 creator A5046405931 @default.
- W2016116859 date "2006-10-25" @default.
- W2016116859 modified "2023-10-18" @default.
- W2016116859 title "Insight into the active sites for the Beckmann rearrangement on porous solids by in situ infrared spectroscopy" @default.
- W2016116859 cites W171406432 @default.
- W2016116859 cites W1964743079 @default.
- W2016116859 cites W1967734646 @default.
- W2016116859 cites W1969243672 @default.
- W2016116859 cites W1979639819 @default.
- W2016116859 cites W1998113969 @default.
- W2016116859 cites W2003657142 @default.
- W2016116859 cites W2026100982 @default.
- W2016116859 cites W2031366377 @default.
- W2016116859 cites W2039046905 @default.
- W2016116859 cites W2047631109 @default.
- W2016116859 cites W2048051775 @default.
- W2016116859 cites W2058377298 @default.
- W2016116859 cites W2069015161 @default.
- W2016116859 cites W212759108 @default.
- W2016116859 cites W2128405848 @default.
- W2016116859 cites W2143182428 @default.
- W2016116859 cites W2521929339 @default.
- W2016116859 cites W2950537684 @default.
- W2016116859 cites W2950790388 @default.
- W2016116859 cites W3198140284 @default.
- W2016116859 cites W3501340 @default.
- W2016116859 cites W77840118 @default.
- W2016116859 doi "https://doi.org/10.1016/j.jcat.2006.06.029" @default.
- W2016116859 hasPublicationYear "2006" @default.
- W2016116859 type Work @default.
- W2016116859 sameAs 2016116859 @default.
- W2016116859 citedByCount "51" @default.
- W2016116859 countsByYear W20161168592013 @default.
- W2016116859 countsByYear W20161168592014 @default.
- W2016116859 countsByYear W20161168592015 @default.
- W2016116859 countsByYear W20161168592016 @default.
- W2016116859 countsByYear W20161168592017 @default.
- W2016116859 countsByYear W20161168592018 @default.
- W2016116859 countsByYear W20161168592019 @default.
- W2016116859 countsByYear W20161168592020 @default.
- W2016116859 countsByYear W20161168592021 @default.
- W2016116859 countsByYear W20161168592022 @default.
- W2016116859 countsByYear W20161168592023 @default.
- W2016116859 crossrefType "journal-article" @default.
- W2016116859 hasAuthorship W2016116859A5000454699 @default.
- W2016116859 hasAuthorship W2016116859A5005652685 @default.
- W2016116859 hasAuthorship W2016116859A5011530797 @default.
- W2016116859 hasAuthorship W2016116859A5044747959 @default.
- W2016116859 hasAuthorship W2016116859A5046405931 @default.
- W2016116859 hasConcept C153642686 @default.
- W2016116859 hasConcept C161790260 @default.
- W2016116859 hasConcept C178790620 @default.
- W2016116859 hasConcept C185592680 @default.
- W2016116859 hasConcept C2776020506 @default.
- W2016116859 hasConcept C2777581007 @default.
- W2016116859 hasConcept C2778077586 @default.
- W2016116859 hasConcept C2781033381 @default.
- W2016116859 hasConcept C82776694 @default.
- W2016116859 hasConcept C86381522 @default.
- W2016116859 hasConceptScore W2016116859C153642686 @default.
- W2016116859 hasConceptScore W2016116859C161790260 @default.
- W2016116859 hasConceptScore W2016116859C178790620 @default.
- W2016116859 hasConceptScore W2016116859C185592680 @default.
- W2016116859 hasConceptScore W2016116859C2776020506 @default.
- W2016116859 hasConceptScore W2016116859C2777581007 @default.
- W2016116859 hasConceptScore W2016116859C2778077586 @default.
- W2016116859 hasConceptScore W2016116859C2781033381 @default.
- W2016116859 hasConceptScore W2016116859C82776694 @default.
- W2016116859 hasConceptScore W2016116859C86381522 @default.
- W2016116859 hasIssue "2" @default.
- W2016116859 hasLocation W20161168591 @default.
- W2016116859 hasOpenAccess W2016116859 @default.
- W2016116859 hasPrimaryLocation W20161168591 @default.
- W2016116859 hasRelatedWork W1576300119 @default.
- W2016116859 hasRelatedWork W1577437069 @default.
- W2016116859 hasRelatedWork W2031071489 @default.
- W2016116859 hasRelatedWork W2032875412 @default.
- W2016116859 hasRelatedWork W2037379794 @default.
- W2016116859 hasRelatedWork W2374253210 @default.
- W2016116859 hasRelatedWork W2589080065 @default.
- W2016116859 hasRelatedWork W2841266425 @default.
- W2016116859 hasRelatedWork W309743204 @default.
- W2016116859 hasRelatedWork W4311421630 @default.
- W2016116859 hasVolume "243" @default.
- W2016116859 isParatext "false" @default.
- W2016116859 isRetracted "false" @default.
- W2016116859 magId "2016116859" @default.
- W2016116859 workType "article" @default.