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• W2016116964 abstract "A novel copper-catalyzed one-pot cross-coupling of β-ketoacids with in situ generated trifluorodiazoethane has been developed. This reaction provides a direct and efficient method, in which one CC bond and one CO bond were formed in a carbenoid center with concomitant denitrogenation–dehydrogenation–decarboxylation, to afford trifluoromethylated aldol products. In several preliminary experiments, good to high enantioselectivities were also obtained." @default.
• W2016116964 created "2016-06-24" @default.
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• W2016116964 date "2014-05-30" @default.
• W2016116964 modified "2023-09-27" @default.
• W2016116964 title "Copper-Catalyzed One-Pot Denitrogenative-Dehydrogenative-Decarboxylative Coupling of β-Ketoacids with Trifluorodiazoethane: Facile Access to Trifluoromethylated Aldol Products" @default.
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• W2016116964 doi "https://doi.org/10.1002/chem.201403073" @default.
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