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- W2016120122 abstract "The stability constants and enthalpies of formation for the formation of the lanthanide monomalonato complexes have been determined by potentiometric and calorimetric titrations in solutions of 0·10 M (NaClO4) and 2·00 M (NaClO4) ionic strength. The formation of the dimalonato complexes of the heavier lanthanide was measured in solutions of 0·10 M (NaClO4). The values for the stability constants agreed with a model of ionic bonding. The pattern of the stability constant variation with lanthanide atomic number for the bidentate malonate complexation differed from that for the monodentate acetate complexing. The values of ΔH and TΔS are comparable for formation of the monomalonato and the diacetate complexes although the pattern of variation differ." @default.
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- W2016120122 title "Malonate complexing of lanthanide ions" @default.
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- W2016120122 doi "https://doi.org/10.1016/0022-1902(72)80588-8" @default.
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