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- W2016123548 abstract "Equilibria involved in the interaction of uranyl ion and phthalic, maleic, oxalic, malonic, succinic and propane-1,2,3-tricarboxylic acids in aqueous solutions have been investigated by means of potentiometric measurement of hydrogen ion concentration at 25° and ionic strength 1·00 (KNO3). Phthalic and maleic acids form complexes with a 1:1 molar ratio of ligand to metal ion, with log K1 = 4·38 ± 0·03 and 4·46 ± 0·05, respectively. Malonic acid forms complexes having molar ratios of 1:1 and 1:2, with log K1 = 5·66 ± 0·02 and log K2 = 4·00 ± 0·02. Oxalic acid interacts strongly with uranyl ion to form a complex having a 1:2 molar ratio of metal to ligand (log β2 = 9·1 ± 0·2). The interactions of uranyl ion with succinic and with 1,2,3-propane tricarboxylic (tricarballylic) acid are very weak. Potentiometric measurements carried out over a wide range of concentration indicate that all of these ligands form only mononuclear uranyl chelates in the pH range 2–4." @default.
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- W2016123548 title "Equilibrium studies of uranyl complexes—IV Reactions with carboxylic acids" @default.
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- W2016123548 doi "https://doi.org/10.1016/0022-1902(67)80057-5" @default.
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