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• W2016127771 abstract "Alternative light water reactor fuel cladding materials are being investigated to replace Zircaloy for enhanced accident tolerance, which involves oxidation resistance to steam environments at ≧1200°C for short times. As chromia-forming alloys and Ni-containing alloys are both undesirable for this application, the focus has been on FeCrAl, although NiAl was used to evaluate the effect of steam oxidation at 1600°C for this study. For commercial and model FeCrAlY alloys, a critical Cr–Al composition was identified for 1 bar isothermal steam (100% H2O) oxidation resistance at 1200°C, which differed for exposures in Ar–50%H2O at the same temperature. Alloys with lower Cr and Al contents were not able to form a protective alumina scale under these conditions. To simulate the accident scenario, exposures were also conducted in steam with the temperature rising 5°C min−1 to 1500°C for the most oxidation resistant alloys. Using thermogravimetry, the maximum use temperature for candidate alloys was determined for different Cr and Al contents. Minor additions such as Y and Ti appeared to be beneficial for oxidation resistance. Similar to prior studies, alumina scales formed in air and in steam appeared to have only subtle differences in microstructure." @default.
• W2016127771 created "2016-06-24" @default.
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• W2016127771 date "2015-01-01" @default.
• W2016127771 modified "2023-10-01" @default.
• W2016127771 title "Effect of steam on high temperature oxidation behaviour of alumina-forming alloys" @default.
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• W2016127771 doi "https://doi.org/10.1179/0960340914z.00000000058" @default.
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