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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016129189> ?p ?o ?g. }

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• W2016129189 abstract "An efficient method for the asymmetric gold(I)-catalyzed preparation of medium sized rings has been developed. The method provides 7- to 9-membered rings in excellent yield. High enantioselectivities can be achieved for 7- and 8-membered ring products employing chiral gold(I) complexes. The results provide insight into the mechanism, showing the fluxional nature of gold(I)-stabilized vinyl carbenoid intermediates." @default.
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• W2016129189 date "2009-01-22" @default.
• W2016129189 modified "2023-10-01" @default.
• W2016129189 title "Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation" @default.
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• W2016129189 doi "https://doi.org/10.1021/ja8085005" @default.
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