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- W2016133787 abstract "Abstract A stereocontrolled and enantioselective synthesis of the branched 6-amino-4,6-deoxyheptopyranuronic acid component of amipurimycin is reported. Key stages in the synthesis include the stereodivergent assembly of the dihydropyrones 12 and 14 from serinal derivatives (S)-10 and (R)-10, elaboration of the tetrahydropyran ring to give 26 and 31, and finally, introduction of the cis-2-aminocyclopentanecarboxylic acid moiety to produce the diastereomeric peptides 28 29 and 32 33 ." @default.
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- W2016133787 date "2010-06-19" @default.
- W2016133787 modified "2023-09-25" @default.
- W2016133787 title "ChemInform Abstract: Stereocontrolled and Enantioselective Synthesis of the Branched 6-Amino-4,6-deoxyheptopyranuronic Acid Component of Amipurimycin." @default.
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- W2016133787 doi "https://doi.org/10.1002/chin.199846247" @default.
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