Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016135564> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2016135564 abstract "Electro-optical, calorimetric, x-ray, and dielectric measurements are reported on a mixture containing a bent-core liquid crystal 4-chloro-1,3-phenylinebis [4-(4-n-tetradecyloxyphenyliminomethyl) benzoate] mixed with the nonpolar solvent n-hexadecane (HEX). It is observed that the addition of HEX depresses the isotropic-to-smectic phase transition temperature, but the crystallization temperature does not change considerably. Instead, the texture of the crystalline phase changes and, at sufficiently high concentrations of HEX (>20 wt %), an optically isotropic phase appears. Above 40 wt % HEX concentrations, the mesophase completely disappears and a direct isotropic solid-to-isotropic liquid transition takes place. At increasing HEX concentration, the transition enthalpies, the layer ordering, and the magnitude of the electric polarization decrease. X-ray studies reveal that HEX molecules pack in between the smectic layers, resulting in an increase of the layer spacing by about 3 A. The increase of the layer spacing saturates at 5 wt % of HEX. The phase segregation observed seems to be due to steric interactions between the flexible HEX molecules and the rigid bent cores of the liquid crystal molecules." @default.
- W2016135564 created "2016-06-24" @default.
- W2016135564 creator A5013394163 @default.
- W2016135564 creator A5051767733 @default.
- W2016135564 creator A5064834523 @default.
- W2016135564 creator A5073167795 @default.
- W2016135564 creator A5079722693 @default.
- W2016135564 date "2002-09-24" @default.
- W2016135564 modified "2023-10-16" @default.
- W2016135564 title "Nanophase segregation of nonpolar solvents in smectic liquid crystals of bent-shape molecules" @default.
- W2016135564 cites W1641835130 @default.
- W2016135564 cites W1964466719 @default.
- W2016135564 cites W1987087426 @default.
- W2016135564 cites W2003841428 @default.
- W2016135564 cites W2012587614 @default.
- W2016135564 cites W2020810037 @default.
- W2016135564 cites W2024091718 @default.
- W2016135564 cites W2026804779 @default.
- W2016135564 cites W2044118480 @default.
- W2016135564 cites W2046437732 @default.
- W2016135564 cites W2051118642 @default.
- W2016135564 cites W2086766038 @default.
- W2016135564 cites W2090766114 @default.
- W2016135564 cites W2151034073 @default.
- W2016135564 doi "https://doi.org/10.1103/physreve.66.031708" @default.
- W2016135564 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12366137" @default.
- W2016135564 hasPublicationYear "2002" @default.
- W2016135564 type Work @default.
- W2016135564 sameAs 2016135564 @default.
- W2016135564 citedByCount "21" @default.
- W2016135564 countsByYear W20161355642014 @default.
- W2016135564 countsByYear W20161355642015 @default.
- W2016135564 countsByYear W20161355642017 @default.
- W2016135564 countsByYear W20161355642018 @default.
- W2016135564 countsByYear W20161355642021 @default.
- W2016135564 countsByYear W20161355642022 @default.
- W2016135564 crossrefType "journal-article" @default.
- W2016135564 hasAuthorship W2016135564A5013394163 @default.
- W2016135564 hasAuthorship W2016135564A5051767733 @default.
- W2016135564 hasAuthorship W2016135564A5064834523 @default.
- W2016135564 hasAuthorship W2016135564A5073167795 @default.
- W2016135564 hasAuthorship W2016135564A5079722693 @default.
- W2016135564 hasConcept C120665830 @default.
- W2016135564 hasConcept C121332964 @default.
- W2016135564 hasConcept C13274807 @default.
- W2016135564 hasConcept C133386390 @default.
- W2016135564 hasConcept C138211643 @default.
- W2016135564 hasConcept C149288129 @default.
- W2016135564 hasConcept C159985019 @default.
- W2016135564 hasConcept C178790620 @default.
- W2016135564 hasConcept C184050105 @default.
- W2016135564 hasConcept C185592680 @default.
- W2016135564 hasConcept C192562407 @default.
- W2016135564 hasConcept C26873012 @default.
- W2016135564 hasConcept C2780768339 @default.
- W2016135564 hasConcept C32909587 @default.
- W2016135564 hasConcept C3535393 @default.
- W2016135564 hasConcept C44280652 @default.
- W2016135564 hasConcept C49040817 @default.
- W2016135564 hasConcept C8010536 @default.
- W2016135564 hasConceptScore W2016135564C120665830 @default.
- W2016135564 hasConceptScore W2016135564C121332964 @default.
- W2016135564 hasConceptScore W2016135564C13274807 @default.
- W2016135564 hasConceptScore W2016135564C133386390 @default.
- W2016135564 hasConceptScore W2016135564C138211643 @default.
- W2016135564 hasConceptScore W2016135564C149288129 @default.
- W2016135564 hasConceptScore W2016135564C159985019 @default.
- W2016135564 hasConceptScore W2016135564C178790620 @default.
- W2016135564 hasConceptScore W2016135564C184050105 @default.
- W2016135564 hasConceptScore W2016135564C185592680 @default.
- W2016135564 hasConceptScore W2016135564C192562407 @default.
- W2016135564 hasConceptScore W2016135564C26873012 @default.
- W2016135564 hasConceptScore W2016135564C2780768339 @default.
- W2016135564 hasConceptScore W2016135564C32909587 @default.
- W2016135564 hasConceptScore W2016135564C3535393 @default.
- W2016135564 hasConceptScore W2016135564C44280652 @default.
- W2016135564 hasConceptScore W2016135564C49040817 @default.
- W2016135564 hasConceptScore W2016135564C8010536 @default.
- W2016135564 hasIssue "3" @default.
- W2016135564 hasLocation W20161355641 @default.
- W2016135564 hasLocation W20161355642 @default.
- W2016135564 hasOpenAccess W2016135564 @default.
- W2016135564 hasPrimaryLocation W20161355641 @default.
- W2016135564 hasRelatedWork W1508237915 @default.
- W2016135564 hasRelatedWork W1963820955 @default.
- W2016135564 hasRelatedWork W1972198764 @default.
- W2016135564 hasRelatedWork W1974542429 @default.
- W2016135564 hasRelatedWork W1986237265 @default.
- W2016135564 hasRelatedWork W2009115578 @default.
- W2016135564 hasRelatedWork W2054869206 @default.
- W2016135564 hasRelatedWork W2061724165 @default.
- W2016135564 hasRelatedWork W2158438356 @default.
- W2016135564 hasRelatedWork W2950701132 @default.
- W2016135564 hasVolume "66" @default.
- W2016135564 isParatext "false" @default.
- W2016135564 isRetracted "false" @default.
- W2016135564 magId "2016135564" @default.
- W2016135564 workType "article" @default.