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• W2016142564 abstract "This paper describes the total synthesis of thelephantin G, thus revising the proposed structure 1 to 2. The key steps involved a double Suzuki-Miyaura coupling and an esterification reaction. By a similar strategy, ganbajunins D and E (3 and 4) were also prepared. Compound 2 strongly inhibited TNF (tumor necrosis factor)-alpha production in rat basophilic leukemia (RBL-2H3) cells: IC(50) = 3.5 nM, while a mixture of 1 and its regioisomer 15 showed no such activity." @default.
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• W2016142564 date "2009-05-19" @default.
• W2016142564 modified "2023-10-14" @default.
• W2016142564 title "Structural Revision of Thelephantin G by Total Synthesis and the Inhibitory Activity against TNF-α Production" @default.
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• W2016142564 doi "https://doi.org/10.1021/jo900638b" @default.
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