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- W2016150437 abstract "For the first time, we demonstrated that Tf2O mediated direct dehydrative glycosylation was possible simply with strained olefins, and other typical bases were inhibitors of this reaction. We optimized the glycosylation conditions and found that typical benzyl protected 1-OH pyranosyl donors and certain alcohol acceptors were suitable for our glycosylation system. Furthermore, we found that complete 1,2-trans selectivity and a wider acceptor scope could be achieved with 2-O-Bz 3,4,6-tri-O-Bn pyranosyl donors." @default.
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- W2016150437 date "2014-01-01" @default.
- W2016150437 modified "2023-09-30" @default.
- W2016150437 title "Strained olefin enables triflic anhydride mediated direct dehydrative glycosylation" @default.
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- W2016150437 doi "https://doi.org/10.1039/c4ob01807a" @default.
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