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• W2016156013 abstract "The thermolysis of the NHC triosmium cluster [Os3(Me2Im)(CO)11] (1a; Me2Im = 1,3-dimethylimidazol-2-ylidene) in toluene at reflux temperature sequentially affords the edge-bridged cluster [Os3(µ-H)(µ-κ2-MeImCH2)(CO)10] (2a) and the face-capped derivative [Os3(µ-H)2(µ3-κ2-MeImCH)(CO)9] (3a). These products result from the sequential oxidative addition of one (2a) and two (3a) N–methyl C–H bonds of the original NHC ligand. The related face-capped triruthenium cluster [Ru3(µ-H)2(µ3-κ2-MeImCH)(CO)9] (3b) has been prepared by heating the NHC triruthenium cluster [Ru3(Me2Im)(CO)11] (1b) in THF at reflux temperature. In this case, the pentanuclear derivatives [Ru5(Me2Im)(µ4-κ2-CO)(CO)14] (4b) and [Ru5(Me2Im)2(µ4-κ2-CO)(CO)13] (5b) are minor reaction products, but a ruthenium cluster analogous to 2a has not been obtained. The face-capped oxazole-derived NHC triruthenium cluster [Ru3(µ-H)2(µ3-κ2-OxCH)(CO)9] (3c; MeOx = N-methyloxazol-2-ylidene) is the only isolated product of the thermolysis of [Ru3(MeOx)(CO)11] (1c) in THF at reflux temperature" @default.
• W2016156013 created "2016-06-24" @default.
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• W2016156013 date "2008-01-01" @default.
• W2016156013 modified "2023-09-25" @default.
• W2016156013 title "Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters" @default.
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• W2016156013 doi "https://doi.org/10.1039/b718770j" @default.
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