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• W2016162956 abstract "A green and facile method was developed to prepare a novel hybrid nanocomposite that consisted of one-dimensional multi-walled carbon nanotubes (MWCNTs) and two-dimensional graphene oxide (GO) sheets. The as-prepared three-dimensional GO–MWCNTs hybrid nanocomposites exhibit excellent water-solubility owing to the high hydrophilicity of GO components; meanwhile, a certain amount of MWCNTs loaded on the surface of GO sheets through π–π interaction seem to be “dissolved” in water. Moreover, the graphene(G)-MWCNTs nanocomposites with excellent conductivity were obtained conveniently by the direct electrochemical reduction of GO–MWCNTs nanocomposites. Seeing that there is a good synergistic effect between MWCNTs and graphene components in enhancing preconcentration efficiency of metal ions and accelerating electron transfer rate at G-MWCNTs/electrolyte interface, the G-MWCNTs nanocomposites possess fast, simultaneous and sensitive detection performance for trace amounts of heavy metal ions. The electrochemical results demonstrate that the G-MWCNTs nanocomposites can act as a kind of practical sensing material to simultaneously determine Pb2+ and Cd2+ ions in terms of anodic stripping voltammetry (ASV). The linear calibration plots for Pb2+ and Cd2+ ranged from 0.5 μg L−1 to 30 μg L−1. The detection limits were determined to be 0.2 μg L−1 (S/N = 3) for Pb2+ and 0.1 μg L−1 (S/N = 3) for Cd2+ in the case of a deposition time of 180 s. It is worth mentioning that the G-MWCNTs modified electrodes were successfully applied to the simultaneous detection of Cd2+ and Pb2+ ions in real electroplating effluent samples containing lots of surface active impurities, showing a good application prospect in the determination of trace amounts of heavy metals." @default.
• W2016162956 created "2016-06-24" @default.
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• W2016162956 date "2014-12-01" @default.
• W2016162956 modified "2023-10-17" @default.
• W2016162956 title "Ultrasensitive and simultaneous detection of heavy metal ions based on three-dimensional graphene-carbon nanotubes hybrid electrode materials" @default.
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• W2016162956 doi "https://doi.org/10.1016/j.aca.2014.09.010" @default.
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