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- W2016172519 abstract "The hydrogen abstraction reaction between atomic chlorine and C–H stretch-excited CHD3 was studied under crossed-beam conditions. Prior to collisions, an infrared (IR) laser was used to pump up a fraction of CHD3 to ν1 = 1. A time-sliced velocity imaging technique was exploited to image the recoil velocity distribution of the state-selected product CD3(ν = 0). For energetic reasons, the IR-on image shows severely overlapped features arising from both the excited and the un-pumped ground-state reagents. A novel threshold method was then developed to directly determine the fraction of IR-excited CHD3 reagents, which in turn enables us to disentangle the state-selected dynamics from the overlapped images. The results reveal significant differences from previous experimental reports." @default.
- W2016172519 created "2016-06-24" @default.
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- W2016172519 creator A5042146252 @default.
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- W2016172519 date "2007-01-01" @default.
- W2016172519 modified "2023-09-24" @default.
- W2016172519 title "Disentangling mode-specific reaction dynamics from overlapped images" @default.
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- W2016172519 doi "https://doi.org/10.1039/b614307e" @default.
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