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- W2016174557 abstract "Molar heat capacities between 95 and 260 K, molar enthalpies of fusion, and melting temperatures are reported for the structure-II clathrate hydrates of propylene oxide, 1,3-dioxolane, 2,5-dihydrofuran, and 1,3-dioxane. All properties show dependence on the nature of the hydrate former. The molar enthalpies of fusion of the hydrates are lower by 4 to 12 per cent and the molar heat capacities are higher by 16 to 28 per cent than the corresponding values for ice. The molar heat capacities of the hydrates show a linear correlation with the corresponding unit-cell constants. An analysis of the heat-capacity results indicates that in the temperature range 95 to 260 K, the heat capacity of the empty hydrate lattice is greater than that of ice and its temperature dependence is different from that of ice." @default.
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- W2016174557 title "Heat capacities in the range 95 to 260 K and enthalpies of fusion for structure-II clathrate hydrates of some cyclic ethers" @default.
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- W2016174557 doi "https://doi.org/10.1016/0021-9614(85)90015-1" @default.
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