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• W2016175330 abstract "Nanoparticles of palladium were synthesized by a `ship-in-a-bottle' technique in supercages of Y-zeolite. The ions of Pd2+ were introduced into the zeolite by ion-exchange between PdCl2 and NaY zeolite. They were then reduced by an electrochemical method and assembled to form nanoparticals by admission and release of CO. The electrode of palladium-loading zeolite film was characterized by cyclic voltammetry, and the adsorption of carbon monoxide on the electrode was studied using in situ electrochemical FTIR reflection spectroscopy. A novel phenomenon of enhanced IR absorption (EIRA) was observed for the first time. In comparison with CO adsorbed on a massive Pd electrode, the IR absorption of CO adsorbed on nanoparticles of Pd confined in supercages of Y-zeolite has been enhanced to about 51 times." @default.
• W2016175330 created "2016-06-24" @default.
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• W2016175330 date "2001-08-01" @default.
• W2016175330 modified "2023-09-25" @default.
• W2016175330 title "Novel phenomenon of enhancement of IR absorption of CO adsorbed on nanoparticles of Pd confined in supercages of Y-zeolite" @default.
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• W2016175330 doi "https://doi.org/10.1016/s0009-2614(01)00812-0" @default.
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