Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016176547> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2016176547 endingPage "36" @default.
- W2016176547 startingPage "31" @default.
- W2016176547 abstract "The germylenes bis[bis(trimethylsilyl)amido]germanium (1a) and bis[t-butyl-trimethylsilyl]amido]germanium (1b) were reacted with N-phenyl-p-quinoneimine (2) to give copolymers (3a and 3b) with alternating tetravalent germanium and p-aminophenol units. The copolymerization took place smoothly at 0°C without added catalyst or initiator. 1 acted as a reductant monomer, and 2 acted as an oxidant monomer (oxidation-reduction alternating copolymerization). Product copolymers were obtained in very high yields and had high molecular weights. The copolymers were soluble in toluene, benzene, n-hexane and chloroform, whereas they were insoluble in acetonitrile and acetone. Additionally, they were stable toward hydrolytic degradation. Electron spin resonance (ESR) spectroscopic studies of the reaction suggested a structure of a stable germyl radical and a plausible mechanism of biradical copolymerization. Germylenes (1a and 1b) reacted with p-quinoneimine (2) to give copolymers (3a and 3b) having a tetravalent germanium unit and a p-aminophenol unit, alternatively. The copolymerization took place at 0°C smoothly without added catalyst or initiator. 1 acted as a reductant monomer whereas 2 as an oxidant monomer (oxidation-reduction alternating copolymerization). Soluble copolymers were obtained in very high yields, having high molecular weight. ESR spectroscopic studies of the reaction suggested a structure of stable germyl radical and a biradical copolymerization mechanism." @default.
- W2016176547 created "2016-06-24" @default.
- W2016176547 creator A5005593466 @default.
- W2016176547 creator A5006210799 @default.
- W2016176547 creator A5040467316 @default.
- W2016176547 creator A5055631368 @default.
- W2016176547 date "2014-10-08" @default.
- W2016176547 modified "2023-10-17" @default.
- W2016176547 title "Oxidation-reduction alternating copolymerization of germylene and N-phenyl-p-quinoneimine" @default.
- W2016176547 cites W120533975 @default.
- W2016176547 cites W1488231006 @default.
- W2016176547 cites W1966690187 @default.
- W2016176547 cites W1978818949 @default.
- W2016176547 cites W1983405111 @default.
- W2016176547 cites W1988099159 @default.
- W2016176547 cites W2001926534 @default.
- W2016176547 cites W2013460632 @default.
- W2016176547 cites W2019382338 @default.
- W2016176547 cites W2022570965 @default.
- W2016176547 cites W2024079820 @default.
- W2016176547 cites W2024658434 @default.
- W2016176547 cites W2031488033 @default.
- W2016176547 cites W2038731829 @default.
- W2016176547 cites W2040138617 @default.
- W2016176547 cites W2051192523 @default.
- W2016176547 cites W2052550029 @default.
- W2016176547 cites W2054241113 @default.
- W2016176547 cites W2055352698 @default.
- W2016176547 cites W2055678516 @default.
- W2016176547 cites W2057449601 @default.
- W2016176547 cites W2067292805 @default.
- W2016176547 cites W2068014269 @default.
- W2016176547 cites W2077853818 @default.
- W2016176547 cites W2083847520 @default.
- W2016176547 cites W2091505568 @default.
- W2016176547 cites W2122717690 @default.
- W2016176547 cites W2950591610 @default.
- W2016176547 cites W2951319748 @default.
- W2016176547 cites W4211193477 @default.
- W2016176547 doi "https://doi.org/10.1038/pj.2014.84" @default.
- W2016176547 hasPublicationYear "2014" @default.
- W2016176547 type Work @default.
- W2016176547 sameAs 2016176547 @default.
- W2016176547 citedByCount "3" @default.
- W2016176547 countsByYear W20161765472016 @default.
- W2016176547 countsByYear W20161765472017 @default.
- W2016176547 countsByYear W20161765472022 @default.
- W2016176547 crossrefType "journal-article" @default.
- W2016176547 hasAuthorship W2016176547A5005593466 @default.
- W2016176547 hasAuthorship W2016176547A5006210799 @default.
- W2016176547 hasAuthorship W2016176547A5040467316 @default.
- W2016176547 hasAuthorship W2016176547A5055631368 @default.
- W2016176547 hasBestOaLocation W20161765471 @default.
- W2016176547 hasConcept C155647269 @default.
- W2016176547 hasConcept C15920480 @default.
- W2016176547 hasConcept C161790260 @default.
- W2016176547 hasConcept C166940927 @default.
- W2016176547 hasConcept C178790620 @default.
- W2016176547 hasConcept C185592680 @default.
- W2016176547 hasConcept C188027245 @default.
- W2016176547 hasConcept C2777000832 @default.
- W2016176547 hasConcept C2777691172 @default.
- W2016176547 hasConcept C2778142098 @default.
- W2016176547 hasConcept C521977710 @default.
- W2016176547 hasConcept C75473681 @default.
- W2016176547 hasConceptScore W2016176547C155647269 @default.
- W2016176547 hasConceptScore W2016176547C15920480 @default.
- W2016176547 hasConceptScore W2016176547C161790260 @default.
- W2016176547 hasConceptScore W2016176547C166940927 @default.
- W2016176547 hasConceptScore W2016176547C178790620 @default.
- W2016176547 hasConceptScore W2016176547C185592680 @default.
- W2016176547 hasConceptScore W2016176547C188027245 @default.
- W2016176547 hasConceptScore W2016176547C2777000832 @default.
- W2016176547 hasConceptScore W2016176547C2777691172 @default.
- W2016176547 hasConceptScore W2016176547C2778142098 @default.
- W2016176547 hasConceptScore W2016176547C521977710 @default.
- W2016176547 hasConceptScore W2016176547C75473681 @default.
- W2016176547 hasIssue "1" @default.
- W2016176547 hasLocation W20161765471 @default.
- W2016176547 hasOpenAccess W2016176547 @default.
- W2016176547 hasPrimaryLocation W20161765471 @default.
- W2016176547 hasRelatedWork W1758771194 @default.
- W2016176547 hasRelatedWork W1971295819 @default.
- W2016176547 hasRelatedWork W1977640147 @default.
- W2016176547 hasRelatedWork W2007097131 @default.
- W2016176547 hasRelatedWork W2070572038 @default.
- W2016176547 hasRelatedWork W2079618202 @default.
- W2016176547 hasRelatedWork W2121842181 @default.
- W2016176547 hasRelatedWork W2357437595 @default.
- W2016176547 hasRelatedWork W2387446634 @default.
- W2016176547 hasRelatedWork W2949249581 @default.
- W2016176547 hasVolume "47" @default.
- W2016176547 isParatext "false" @default.
- W2016176547 isRetracted "false" @default.
- W2016176547 magId "2016176547" @default.
- W2016176547 workType "article" @default.