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• W2016177658 abstract "A metal-free catalytic system with N,N′,N″-trihydroxyisocyanuric acid (THICA) as the catalyst for the oxidation of nitrotoluenes is introduced, and a novel Pd-free approach for the synthesis of THICA was developed. In a solution of acetic acid, THICA and concentrated nitric acid, nitrotoluenes especially polynitrotoluenes such as 2,4,6-trinitrotoluene (TNT), were converted into the desired carboxylic acids under 0.2 MPa of O2 at 100 °C with yields up to 99%. THICA was synthesized from N-hydroxyphtalimide through a four-step synthesis in a total yield of 46%. A possible mechanism of this catalytic process was proposed where NO2 and nitric acid first induced a radical of THICA, which then abstracts a hydrogen atom from the methyl on the aromatic ring to form a benzyl radical. This radical then initiates subsequent reactions. The production of the benzyl radical was supported by ESR measurements." @default.
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• W2016177658 date "2010-12-01" @default.
• W2016177658 modified "2023-10-07" @default.
• W2016177658 title "A metal-free aerobic oxidation of nitrotoluenes catalyzed by N,N′,N″-trihydroxyisocyanuric acid (THICA) and a novel approach to the catalyst" @default.
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• W2016177658 doi "https://doi.org/10.1016/j.jhazmat.2010.08.049" @default.
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