FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016183765> ?p ?o ?g. }

• W2016183765 endingPage "2690" @default.
• W2016183765 startingPage "2672" @default.
• W2016183765 abstract "A family of highly stable (poly)perfluoroalky-lated metallic nitride cluster fullerenes was prepared in high-temperature reactions and characterized by spectroscopic (MS, 19F NMR, UV−vis/NIR, ESR), structural and electrochemical methods. For two new compounds, Sc3N@C80(CF3)10 and Sc3N@C80(CF3)12, single crystal X-ray structures are determined. Addition pattern guidelines for endohedral fullerene derivatives with bulky functional groups are formulated as a result of experimental (19F NMR spectroscopy and single crystal X-ray diffraction) studies and exhaustive quantum chemical calculations of the structures of Sc3N@C80(CF3)n (n = 2-16). Electrochemical studies revealed that Sc3N@C80(CF3)n derivatives are easier to reduce than Sc3N@C80, the shift of E1/2 potentials ranging from +0.11 V (n = 2) to +0.42 V (n = 10). Stable radical anions of Sc3N@C80(CF3)n were generated in solution and characterized by ESR spectroscopy, revealing their 45Sc hyperfine structure. Facile further functionalizations via cycloadditions or radical additions were achieved for trifluoromethylated Sc3N@C80 making them attractive versatile platforms for the design of molecular and supramolecular materials of fundamental and practical importance." @default.
• W2016183765 created "2016-06-24" @default.
• W2016183765 creator A5003472296 @default.
• W2016183765 creator A5009205853 @default.
• W2016183765 creator A5012671580 @default.
• W2016183765 creator A5021115977 @default.
• W2016183765 creator A5026526956 @default.
• W2016183765 creator A5027903798 @default.
• W2016183765 creator A5028808065 @default.
• W2016183765 creator A5040666345 @default.
• W2016183765 creator A5046845725 @default.
• W2016183765 creator A5046928138 @default.
• W2016183765 creator A5049532515 @default.
• W2016183765 creator A5068012461 @default.
• W2016183765 creator A5072396055 @default.
• W2016183765 creator A5086175062 @default.
• W2016183765 creator A5088665202 @default.
• W2016183765 date "2011-02-04" @default.
• W2016183765 modified "2023-10-03" @default.
• W2016183765 title "Poly(perfluoroalkylation) of Metallic Nitride Fullerenes Reveals Addition-Pattern Guidelines: Synthesis and Characterization of a Family of Sc₃N@C₈₀(CF₃)_<i>n</i> (<i>n</i> = 2−16) and Their Radical Anions" @default.
• W2016183765 cites W1515575861 @default.
• W2016183765 cites W1564888672 @default.
• W2016183765 cites W1674015533 @default.
• W2016183765 cites W183060239 @default.
• W2016183765 cites W1963712833 @default.
• W2016183765 cites W1964008960 @default.
• W2016183765 cites W1964078174 @default.
• W2016183765 cites W1964723698 @default.
• W2016183765 cites W1965609410 @default.
• W2016183765 cites W1969652545 @default.
• W2016183765 cites W1972639352 @default.
• W2016183765 cites W1972692015 @default.
• W2016183765 cites W1976156678 @default.
• W2016183765 cites W1977145846 @default.
• W2016183765 cites W1983120331 @default.
• W2016183765 cites W1986164512 @default.
• W2016183765 cites W1987086277 @default.
• W2016183765 cites W1988031364 @default.
• W2016183765 cites W1988124685 @default.
• W2016183765 cites W1991245235 @default.
• W2016183765 cites W1995499019 @default.
• W2016183765 cites W1997541696 @default.
• W2016183765 cites W2002175985 @default.
• W2016183765 cites W2008580435 @default.
• W2016183765 cites W2009638987 @default.
• W2016183765 cites W2011778170 @default.
• W2016183765 cites W2018384868 @default.
• W2016183765 cites W2021187273 @default.
• W2016183765 cites W2022676672 @default.
• W2016183765 cites W2029187946 @default.
• W2016183765 cites W2034294293 @default.
• W2016183765 cites W2036069481 @default.
• W2016183765 cites W2042476195 @default.
• W2016183765 cites W2044022926 @default.
• W2016183765 cites W2044266485 @default.
• W2016183765 cites W2046327260 @default.
• W2016183765 cites W2048508129 @default.
• W2016183765 cites W2050095555 @default.
• W2016183765 cites W2051783550 @default.
• W2016183765 cites W2055941329 @default.
• W2016183765 cites W2057074050 @default.
• W2016183765 cites W2057243911 @default.
• W2016183765 cites W2058997397 @default.
• W2016183765 cites W2060410316 @default.
• W2016183765 cites W2065077283 @default.
• W2016183765 cites W2065591555 @default.
• W2016183765 cites W2070447640 @default.
• W2016183765 cites W2072492981 @default.
• W2016183765 cites W2076854402 @default.
• W2016183765 cites W2081438250 @default.
• W2016183765 cites W2082499437 @default.
• W2016183765 cites W2082618661 @default.
• W2016183765 cites W2085236991 @default.
• W2016183765 cites W2085879513 @default.
• W2016183765 cites W2085919319 @default.
• W2016183765 cites W2100089199 @default.
• W2016183765 cites W2100667298 @default.
• W2016183765 cites W2104147788 @default.
• W2016183765 cites W2111795914 @default.
• W2016183765 cites W2125093363 @default.
• W2016183765 cites W2130411884 @default.
• W2016183765 cites W2141448242 @default.
• W2016183765 cites W2142277026 @default.
• W2016183765 cites W2149111565 @default.
• W2016183765 cites W2149811186 @default.
• W2016183765 cites W2168046755 @default.
• W2016183765 cites W2169700285 @default.
• W2016183765 cites W2314999299 @default.
• W2016183765 cites W2321403861 @default.
• W2016183765 cites W2334398855 @default.
• W2016183765 cites W2952874882 @default.
• W2016183765 cites W4319704865 @default.
• W2016183765 doi "https://doi.org/10.1021/ja109462j" @default.
• W2016183765 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21294511" @default.
• W2016183765 hasPublicationYear "2011" @default.
• W2016183765 type Work @default.
• W2016183765 sameAs 2016183765 @default.
• W2016183765 citedByCount "66" @default.

• next