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- W2016185767 abstract "We have devised a new caged GABA based on ruthenium bipyridyl coordination chemistry. This phototrigger delivers GABA upon irradiation with wavelengths up to 532 nm undergoing heterolytic photocleavage, in a clean and very fast (a few nanoseconds) photoreaction. With an absorptivity coefficient εMAX = 5300 M−1 cm−1 at 447 nm and a quantum efficiency ϕ ~ 0.09, RuBiGABA-2 is among the most active caged-GABAs, especially at long wavelengths. This highly hydrophilic caged GABA can be synthesized in a simple one-pot reaction. The synthesis, chemical characterization and photochemical properties are presented. Finally, the usefulness of this caged compound is demonstrated by photodelivering free GABA on leech motoneurons." @default.
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- W2016185767 date "2013-09-01" @default.
- W2016185767 modified "2023-10-01" @default.
- W2016185767 title "RuBiGABA-2: a hydrophilic caged GABA with long wavelength sensitivity" @default.
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- W2016185767 doi "https://doi.org/10.1039/c3pp25248e" @default.
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