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- W201619217 abstract "This status report outlines the results obtained to date of the current research program supported jointly by the Gas Research Institute and the State of Illinois Center for Research on Sulfur in Coal. The overall objective is to obtain data related to the efficient utilization of high-sulfur Illinois coal in a One-Step Desulfurization Process by employing in-situ removal of sulfur using calcium-based sorbents. The project includes a study of fluidization behavior of coal char/sorbent mixtures and the reactions of calcium-based sorbents with sulfur present in the coal during gasification. The tests are conducted in bench-scale units; an 8-inch fluidization column is utilized for fluidization tests, and a thermobalance reactor is used for gas-solid reactions. The test parameters include the choice of sorbent, sorbent size, the effect of temperature on sulfation and sulfidation reactions, the effect of the steam-to-hydrogen sulfide ratio on the sulfidation reaction, the effect of the steam on the sulfation reaction, and the influence of exposure time on sulfation of the presulfided sorbent. The reaction conditions for these reactions have been chosen to be directly applicable to scale-up of the One-Step Desulfurization Process. 7 refs., 9 figs., 11 tabs." @default.
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- W201619217 date "1987-01-01" @default.
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- W201619217 title "Reactions of calcium-based sorbents with sulfur in coal during gasification" @default.
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