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- W2016200426 abstract "Two cyclometalated iridium(III) complexes, (pqcm)2Ir(pic) and (pqca)2Ir(pic) (pqcmH = 2-phenylquinoline-4-carboxylic acid methyl ester, pqcaH = 2-phenylquinoline-4-carboxylic acid adamantanemethyl ester, pic = picolinate), were successfully synthesized and characterized by NMR spectroscopy and mass spectrometry. The photoluminescence spectrum of (pqcm)2Ir(pic) shows emission maximum at 661 nm with a lifetime of 122 ns and quantum yield of ca. 0.028. Replacing the methyl unit with 1-adamantanemethyl unit, the longer lifetime (161 ns) and higher quantum yield (0.040) of (pqca)2Ir(pic) was obtained. Polymer light-emitting devices using these complexes as dopant exhibited intense saturated red emission with CIE coordinates of (0.66,0.29). The devices with 2% doping concentrations of (pqcm)2Ir(pic) have the best performance with a maximum external quantum efficiency of 10.3% and luminance efficiency of 3.97 cd/A. The devices doped (pqca)2Ir(pic) has a higher luminous efficiency (4.17 cd/A) but lower external quantum efficiency (3.65%)." @default.
- W2016200426 created "2016-06-24" @default.
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- W2016200426 date "2012-10-01" @default.
- W2016200426 modified "2023-10-17" @default.
- W2016200426 title "Synthesis and electroluminescent properties of red emissive iridium(III) complexes with ester-substituted phenylquinoline ligands" @default.
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- W2016200426 doi "https://doi.org/10.1016/j.synthmet.2012.06.016" @default.
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