FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016200600> ?p ?o ?g. }

• W2016200600 endingPage "11177" @default.
• W2016200600 startingPage "11176" @default.
• W2016200600 abstract "Two procedures for the alpha-arylation of carbonyl compounds under conditions that are more neutral than those of reactions of aryl halides with alkali metal enolates are reported. The first procedure rests upon the development of catalysts bearing the hindered pentaphenylferrocenyl di-tert-butylphosphine (Q-phos) and the highly reactive dimeric Pd(I) complex {P(t-Bu)3]PdBr}2. By this procedure, zinc enolates prepared from alpha-bromo esters and amides react with aryl halides to form alpha-aryl esters and amides in high yields under mild conditions with 1-2 mol % catalyst and with remarkable functional group tolerance. By the second procedure, silyl ketene and silyl ketimine acetals react with aryl bromides in the presence of substoichiometric zinc fluoride, 1 mol % Pd(dba)2, and 2 mol % P(t-Bu)3 in DMF solvent at 80 degrees C. Reactions of zinc tert-butyl acetate and propionate enolates and trimethylsilyl ketene acetals of tert-butyl propionate and methyl isobutyrate with aryl bromides bearing electron-donating and potentially reactive, base-sensitive electron-withdrawing groups and with pyridyl bromides are reported. In addition, the diastereoselective coupling of phenyl bromide with an imide enolate bearing the Evans auxiliary is reported, and this study shows that racemization of base-sensitive stereocenters does not occur during the coupling process under these more neutral conditions." @default.
• W2016200600 created "2016-06-24" @default.
• W2016200600 creator A5001583157 @default.
• W2016200600 creator A5003609998 @default.
• W2016200600 creator A5013444814 @default.
• W2016200600 creator A5088865204 @default.
• W2016200600 date "2003-08-21" @default.
• W2016200600 modified "2023-10-16" @default.
• W2016200600 title "Palladium-Catalyzed α-Arylation of Esters and Amides under More Neutral Conditions" @default.
• W2016200600 cites W1965783160 @default.
• W2016200600 cites W1967375283 @default.
• W2016200600 cites W1969533214 @default.
• W2016200600 cites W1972611478 @default.
• W2016200600 cites W1979489398 @default.
• W2016200600 cites W1990399082 @default.
• W2016200600 cites W2016346208 @default.
• W2016200600 cites W2029033849 @default.
• W2016200600 cites W2042029110 @default.
• W2016200600 cites W2080925478 @default.
• W2016200600 cites W2087565617 @default.
• W2016200600 cites W2113178062 @default.
• W2016200600 cites W2119016897 @default.
• W2016200600 cites W2140107974 @default.
• W2016200600 cites W2149476429 @default.
• W2016200600 cites W2150805674 @default.
• W2016200600 cites W2164930732 @default.
• W2016200600 cites W2344927577 @default.
• W2016200600 cites W2949241209 @default.
• W2016200600 cites W2951145642 @default.
• W2016200600 cites W3005470321 @default.
• W2016200600 doi "https://doi.org/10.1021/ja036792p" @default.
• W2016200600 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16220921" @default.
• W2016200600 hasPublicationYear "2003" @default.
• W2016200600 type Work @default.
• W2016200600 sameAs 2016200600 @default.
• W2016200600 citedByCount "226" @default.
• W2016200600 countsByYear W20162006002012 @default.
• W2016200600 countsByYear W20162006002013 @default.
• W2016200600 countsByYear W20162006002014 @default.
• W2016200600 countsByYear W20162006002015 @default.
• W2016200600 countsByYear W20162006002016 @default.
• W2016200600 countsByYear W20162006002017 @default.
• W2016200600 countsByYear W20162006002018 @default.
• W2016200600 countsByYear W20162006002019 @default.
• W2016200600 countsByYear W20162006002020 @default.
• W2016200600 countsByYear W20162006002021 @default.
• W2016200600 countsByYear W20162006002022 @default.
• W2016200600 countsByYear W20162006002023 @default.
• W2016200600 crossrefType "journal-article" @default.
• W2016200600 hasAuthorship W2016200600A5001583157 @default.
• W2016200600 hasAuthorship W2016200600A5003609998 @default.
• W2016200600 hasAuthorship W2016200600A5013444814 @default.
• W2016200600 hasAuthorship W2016200600A5088865204 @default.
• W2016200600 hasConcept C155647269 @default.
• W2016200600 hasConcept C161790260 @default.
• W2016200600 hasConcept C168382676 @default.
• W2016200600 hasConcept C178790620 @default.
• W2016200600 hasConcept C185592680 @default.
• W2016200600 hasConcept C2776300020 @default.
• W2016200600 hasConcept C2777000832 @default.
• W2016200600 hasConcept C2778207378 @default.
• W2016200600 hasConcept C2778439535 @default.
• W2016200600 hasConcept C2778874822 @default.
• W2016200600 hasConcept C2780263894 @default.
• W2016200600 hasConcept C2781076698 @default.
• W2016200600 hasConcept C502130503 @default.
• W2016200600 hasConcept C512735826 @default.
• W2016200600 hasConcept C5304478 @default.
• W2016200600 hasConcept C535196362 @default.
• W2016200600 hasConceptScore W2016200600C155647269 @default.
• W2016200600 hasConceptScore W2016200600C161790260 @default.
• W2016200600 hasConceptScore W2016200600C168382676 @default.
• W2016200600 hasConceptScore W2016200600C178790620 @default.
• W2016200600 hasConceptScore W2016200600C185592680 @default.
• W2016200600 hasConceptScore W2016200600C2776300020 @default.
• W2016200600 hasConceptScore W2016200600C2777000832 @default.
• W2016200600 hasConceptScore W2016200600C2778207378 @default.
• W2016200600 hasConceptScore W2016200600C2778439535 @default.
• W2016200600 hasConceptScore W2016200600C2778874822 @default.
• W2016200600 hasConceptScore W2016200600C2780263894 @default.
• W2016200600 hasConceptScore W2016200600C2781076698 @default.
• W2016200600 hasConceptScore W2016200600C502130503 @default.
• W2016200600 hasConceptScore W2016200600C512735826 @default.
• W2016200600 hasConceptScore W2016200600C5304478 @default.
• W2016200600 hasConceptScore W2016200600C535196362 @default.
• W2016200600 hasIssue "37" @default.
• W2016200600 hasLocation W20162006001 @default.
• W2016200600 hasLocation W20162006002 @default.
• W2016200600 hasOpenAccess W2016200600 @default.
• W2016200600 hasPrimaryLocation W20162006001 @default.
• W2016200600 hasRelatedWork W1964437401 @default.
• W2016200600 hasRelatedWork W1992515733 @default.
• W2016200600 hasRelatedWork W2012244682 @default.
• W2016200600 hasRelatedWork W2022738692 @default.
• W2016200600 hasRelatedWork W2049560204 @default.
• W2016200600 hasRelatedWork W2090707283 @default.
• W2016200600 hasRelatedWork W2949701658 @default.
• W2016200600 hasRelatedWork W2952281490 @default.

• next