FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016201583> ?p ?o ?g. }

• W2016201583 endingPage "986" @default.
• W2016201583 startingPage "975" @default.
• W2016201583 abstract "The elimination of Bisphenol A (BPA) from contaminated waters is an urgent challenge. This contribution focuses on BPA degradation by homogeneous Fenton reagent based on reactive ()OH radicals. Pronounced sub-stoichiometric amounts of H(2)O(2) oxidant were used to simulate economically viable processes and operation under not fully controlled conditions, as for example in in situ groundwater remediation. Aside from the most abundant benzenediols and the monohydroxylated BPA intermediate (which were detected as stable intermediates in earlier contributions), a wide array of aromatic products in the molecular weight range between 94 Da (phenol) and approximately 500 Da could be detected, the overwhelming majority of which have not been reported thus far. The identification was carried out by GC/MS analysis of trimethylsilyl ethers. The structural assignments were confirmed through the use of fully deuterated [(2)H(16)] BPA as the substrate, as well as using retention indices calculated on the basis of the increment system. The occurrence of aromatic intermediates larger than BPA, which typically share either a biphenyl- or a diphenylether structure, can be explained by oxidative coupling reactions of stabilized free radicals or by the addition of organoradicals (organocations) onto BPA molecules or benzenediols. The hydroxycyclohexadienyl radical of BPA was recognized to play central role in the degradation pathways. Ring opening products, including lactic, acetic and dicarboxylic acids, could be detected in addition to aromatic intermediates. Since some of those intermediates and products are recalcitrant to further oxidation under the conditions of sub-stoichiometric Fenton reaction, they should be carefully considered when designing and optimizing Fenton-driven remediation systems." @default.
• W2016201583 created "2016-06-24" @default.
• W2016201583 creator A5062196666 @default.
• W2016201583 creator A5072083498 @default.
• W2016201583 creator A5091531804 @default.
• W2016201583 date "2010-05-01" @default.
• W2016201583 modified "2023-10-18" @default.
• W2016201583 title "Aromatic intermediate formation during oxidative degradation of Bisphenol A by homogeneous sub-stoichiometric Fenton reaction" @default.
• W2016201583 cites W1486244460 @default.
• W2016201583 cites W1963592970 @default.
• W2016201583 cites W1964254681 @default.
• W2016201583 cites W1968169887 @default.
• W2016201583 cites W1979055332 @default.
• W2016201583 cites W1986443232 @default.
• W2016201583 cites W1987418454 @default.
• W2016201583 cites W1997004166 @default.
• W2016201583 cites W2000018317 @default.
• W2016201583 cites W2006890927 @default.
• W2016201583 cites W2016262121 @default.
• W2016201583 cites W2019859863 @default.
• W2016201583 cites W2020340887 @default.
• W2016201583 cites W2021516438 @default.
• W2016201583 cites W2027223634 @default.
• W2016201583 cites W2028592952 @default.
• W2016201583 cites W2028671612 @default.
• W2016201583 cites W2030683065 @default.
• W2016201583 cites W2052342420 @default.
• W2016201583 cites W2054642659 @default.
• W2016201583 cites W2055159418 @default.
• W2016201583 cites W2056802620 @default.
• W2016201583 cites W2058215085 @default.
• W2016201583 cites W2063047805 @default.
• W2016201583 cites W2063852494 @default.
• W2016201583 cites W2076958554 @default.
• W2016201583 cites W2082624865 @default.
• W2016201583 cites W2092359789 @default.
• W2016201583 cites W2094424997 @default.
• W2016201583 cites W2143546017 @default.
• W2016201583 cites W2337545831 @default.
• W2016201583 doi "https://doi.org/10.1016/j.chemosphere.2010.03.030" @default.
• W2016201583 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20394961" @default.
• W2016201583 hasPublicationYear "2010" @default.
• W2016201583 type Work @default.
• W2016201583 sameAs 2016201583 @default.
• W2016201583 citedByCount "115" @default.
• W2016201583 countsByYear W20162015832012 @default.
• W2016201583 countsByYear W20162015832013 @default.
• W2016201583 countsByYear W20162015832014 @default.
• W2016201583 countsByYear W20162015832015 @default.
• W2016201583 countsByYear W20162015832016 @default.
• W2016201583 countsByYear W20162015832017 @default.
• W2016201583 countsByYear W20162015832018 @default.
• W2016201583 countsByYear W20162015832019 @default.
• W2016201583 countsByYear W20162015832020 @default.
• W2016201583 countsByYear W20162015832021 @default.
• W2016201583 countsByYear W20162015832022 @default.
• W2016201583 countsByYear W20162015832023 @default.
• W2016201583 crossrefType "journal-article" @default.
• W2016201583 hasAuthorship W2016201583A5062196666 @default.
• W2016201583 hasAuthorship W2016201583A5072083498 @default.
• W2016201583 hasAuthorship W2016201583A5091531804 @default.
• W2016201583 hasConcept C105768512 @default.
• W2016201583 hasConcept C139066938 @default.
• W2016201583 hasConcept C144082473 @default.
• W2016201583 hasConcept C161790260 @default.
• W2016201583 hasConcept C166595027 @default.
• W2016201583 hasConcept C178790620 @default.
• W2016201583 hasConcept C185592680 @default.
• W2016201583 hasConcept C192937433 @default.
• W2016201583 hasConcept C2777691172 @default.
• W2016201583 hasConcept C2777702071 @default.
• W2016201583 hasConcept C2779679103 @default.
• W2016201583 hasConcept C2779684741 @default.
• W2016201583 hasConcept C2780591471 @default.
• W2016201583 hasConcept C41008148 @default.
• W2016201583 hasConcept C75473681 @default.
• W2016201583 hasConcept C76155785 @default.
• W2016201583 hasConceptScore W2016201583C105768512 @default.
• W2016201583 hasConceptScore W2016201583C139066938 @default.
• W2016201583 hasConceptScore W2016201583C144082473 @default.
• W2016201583 hasConceptScore W2016201583C161790260 @default.
• W2016201583 hasConceptScore W2016201583C166595027 @default.
• W2016201583 hasConceptScore W2016201583C178790620 @default.
• W2016201583 hasConceptScore W2016201583C185592680 @default.
• W2016201583 hasConceptScore W2016201583C192937433 @default.
• W2016201583 hasConceptScore W2016201583C2777691172 @default.
• W2016201583 hasConceptScore W2016201583C2777702071 @default.
• W2016201583 hasConceptScore W2016201583C2779679103 @default.
• W2016201583 hasConceptScore W2016201583C2779684741 @default.
• W2016201583 hasConceptScore W2016201583C2780591471 @default.
• W2016201583 hasConceptScore W2016201583C41008148 @default.
• W2016201583 hasConceptScore W2016201583C75473681 @default.
• W2016201583 hasConceptScore W2016201583C76155785 @default.
• W2016201583 hasIssue "10" @default.
• W2016201583 hasLocation W20162015831 @default.
• W2016201583 hasLocation W20162015832 @default.
• W2016201583 hasOpenAccess W2016201583 @default.
• W2016201583 hasPrimaryLocation W20162015831 @default.

• next