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- W2016203651 abstract "A torsion pendulum has been employed to investigate the low temperature (γ) relaxation in epoxy resins and in certain related rigid polymers. In epoxy resin cured with diethylene triamine the relaxation between −80°C and −40°C is caused by the crankshaft type rotation of the segment CH2CH(OH)CH2O. The same is responsible for the lowering of the glassy modulus at 20°C as shown by the increase in the creep compliance of the resin with increasing cure. Low temperature relaxations of various magnitudes have been found in all the following polymers: epoxy resin cured with acid anhydride, phenoxy resin, polycarbonate, polysulfone, polyimide, polyphenylene oxide, Bakelite, and a Friedel-Crafts polymer. It is suggested that these relaxations are caused by some kind of non-rotational wriggling motion of segments containing benzene rings. The temperature of these relaxations may depend on the rigidity of links between the benzene rings." @default.
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- W2016203651 title "Gamma relaxation in epoxy resins and related polymers" @default.
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- W2016203651 doi "https://doi.org/10.1016/0032-3861(70)90027-3" @default.
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