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- W2016204428 abstract "Organic Syntheses via Transition Metal Complexes, 62. – First Carbene Complexes (MCr, W) with Carbohydrate Substituents The first examples of transition metal carbene complexes of carbohydrate derivatives are described: 1,2:5,6–Di-O-isopropyliden-α-D–glucofuranose (2a), 1,2:5,6–di-O-isopropylidene-α-D–allofuranose (2b), and 2,3:5,6–di-O-isopropyliden-α-D–mannofuranose (2c) add regiospecifically at C–3 of alkynylcarbene complexes LnMC(OEt)–CCPh 1 [LnMCr(CO)5 (a), W(CO)5 (b)] to give vinylcarbene complexes LnMC(OEt)–CHC(Ph)–O(sugar) (E/Z)-3a–g in good to excellent yields. As a minor side reaction the alkynyl carbene complex (CO)5WC(OEt)–CCPh (1b) isomerises to give the 1,2–propadienylidene complex (CO)5WCCC(OEt)C6H5 (4b)." @default.
- W2016204428 created "2016-06-24" @default.
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- W2016204428 date "1992-12-01" @default.
- W2016204428 modified "2023-10-17" @default.
- W2016204428 title "Organische Synthesen mit Übergangsmetall–Komplexen, 62. Erste Carbenkomplexe (MCr, W) mit Kohlenhydrat–Substituenten" @default.
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- W2016204428 doi "https://doi.org/10.1002/cber.19921251224" @default.
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