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- W2016206036 abstract "A systematic study of the base-catalysed exchange reactions of a series of gibberellin 7-methyl esters reveals that exchange of the 6-proton for deuterium is apparent only in compounds possessing a 19, 10γ-lactone or the analogous 19-ketone. The favoured mechanism for the participation of the 19-carbonyl function involves attack of the base on the 19-carbonyl giving a tetrahedral intermediate which may then abstract the 6α-proton (Scheme 2)." @default.
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- W2016206036 modified "2023-10-16" @default.
- W2016206036 title "Deuterium exchange at C-6 of gibberellin 7-methyl esters: anchimeric assistance by the 19,10γ-lactone" @default.
- W2016206036 cites W2011400372 @default.
- W2016206036 doi "https://doi.org/10.1016/0040-4039(92)88099-q" @default.
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