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- W2016206941 abstract "Abstract The review concentrates on the major aspects of radical copolymerization of acrylonitrile and methacrylonitrile with various comonomers in biphase media, namely, in thermodynamically bad solvents and precipitators. Some specific features of homopolymerization of nitriles in heterophase media are discussed too, and this makes the treatment of the data on copolymerization more grounded. The effects depending on the topology of the process of copolymerization are picked out and the theories explaining them are presented. Special attention is centered on the peculiarities of the synthesis of hydrophylic copolymers containing nitrile units. The problem of applicability of the scheme of Mayo and Lewis for the systems under study is discussed, emphasizing that the treatment of experimental data in the form of composition diagrams is not “self-controlled.” It is shown that a more sensitive criterion for an estimation of heterophase copolymerization is chemical heterogeneity of copolymers synthesized, namely, integral curves of distribution by composition of copolymers. Phase-transfer-catalyzed copolymerization of unsaturated nitriles as a new kind of heterophase copolymerization is presented." @default.
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- W2016206941 title "Radical Copolymerization of Unsaturated Nitriles in Biphase Media: A Review" @default.
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- W2016206941 doi "https://doi.org/10.1080/03602559108019222" @default.
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