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- W2016208079 abstract "The interaction between poly(methyl methacrylate) (PMMA) and oxidized aluminium surfaces has been studied using Fourier transform infra-red multiple specular reflectance (FTi.r.-MSR) and inelastic electron tunnelling spectroscopy (IETS). FTi.r.-MSR spectra of ultra thin (∼1 nm) PMMA films show an enhancement of the intensity in the low frequency wing of the carbonyl absorption. The peak is shifted to lower frequency and broadened compared to theoretical predictions. This suggests hydrogen bonding between the PMMA carbonyl species and the surface hydroxyl groups. The relative intensity of the carbonyl mode in the IETS spectrum is very low and its frequency is lowered compared to the i.r. result. In addition, a small band is observed at the position of the vs(CO−2) vibration. However, ester bond cleavage and subsequent formation of ionic carboxylate bonds is very unlikely, because it contradicts the FTi.r.-MSR results. This suggests an intrinsically low intensity of carbonyl bands in IETS. The inertness of the lead counter electrode in IETS is discussed. The lead electrode may account for the downward shift of the carbonyl vibration in IETS." @default.
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- W2016208079 title "A combined Fourier transform infra-red multiple specular reflectance and inelastic electron tunnelling spectroscopy study of poly(methyl methacrylate) on oxidized aluminium" @default.
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- W2016208079 doi "https://doi.org/10.1016/0032-3861(91)90187-n" @default.
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