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• W2016209831 abstract "Thermally averaged rate coefficients for vibrational state changes and dissociation from individual vibrational levels in H2-Ar collissions at 4500 K are derived from Monte Carlo quasiclassical trajectory calculations. The rate matrix is completed by linear surprisal interpolation. Relaxation times, induction times, and steady dissociation rates simulating a shock wave experiment are calculated by a matrix-eigenvalue solution of the master equation. Rotational equilibrium is assumed, but vibrational nonequilibrium effects are included in full. The resulting steady dissociation rates are only about 30% less than at equilibrium." @default.
• W2016209831 created "2016-06-24" @default.
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• W2016209831 date "1979-05-01" @default.
• W2016209831 modified "2023-10-18" @default.
• W2016209831 title "Monte Carlo trajectory study of Ar + H2 collisions: Master-equation simulation of a 4500 K shock wave experiment with thermal rotation" @default.
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• W2016209831 doi "https://doi.org/10.1016/0009-2614(79)87031-1" @default.
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