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- W2016227449 abstract "Oxygen reducton (OR) at Pt electrodes in aqueous HClO4 solution (pH = 1.9) is examined at temperature from 5 to 45°C. At all temperatures, two distinct Elogi regions are observed. At low current densities (cd), the Tafel slopes are close to −2.3 RT/F, while at high cds they are close to −2 × 2.3 RT/F. Though the apparent enthalpy of activation at the reversible potential in the low cd region (=60 kJ mole−1) is higher than the apparent enthalpy of activation in the high cd region (=43 kJ mol−1), it is shown that the actual enthalpies of activation, ie the enthalpies at †φ = 0, are the same in both cd regions. The rate determining step of the reaction is, therefore, the same in both cd regions and the observed changes in the Tafel slopes arise from different conditions of adsorption of reaction intermediates in these regions, as previously suggested." @default.
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- W2016227449 date "1986-01-01" @default.
- W2016227449 modified "2023-10-18" @default.
- W2016227449 title "Apparent enthalpies of activation of electrodic oxygen reduction at platinum in different current density regions—I. Acid solution" @default.
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- W2016227449 doi "https://doi.org/10.1016/0013-4686(86)80067-6" @default.
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