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- W2016228733 abstract "The mechanism of the novel dimethyldioxirane (DMD) oxidation of σH adducts (Meisenheimer complexes) generated from nitroarenes and carbanions was elucidated. The proposed mechanism, which is akin to that of the oxidative Nef reaction, is supported by the isolation of the cyclohexadienone intermediate and the lack of a primary kinetic isotopic effect. Protic solvents (H2O, MeOH) enhance the reactivity of DMD through intermolecular hydrogen bonding." @default.
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- W2016228733 date "2000-01-28" @default.
- W2016228733 modified "2023-10-18" @default.
- W2016228733 title "On the Mechanism of the Dimethyldioxirane Oxidation of σ<sup>H</sup> Adducts (Meisenheimer Complexes) Generated from Nitroarenes and Carbanions" @default.
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- W2016228733 doi "https://doi.org/10.1021/jo9915628" @default.
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