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• W2016245628 abstract "The molecule (PNPR)Re(H)4 (PNPR = (R2PCH2SiMe2)2N, R = iPr or cyclohexyl) reacts at 20 degrees C with 2 mol of cyclohexene to form equimolar cyclohexane and (PNPR)Re(H)2[=C(CH2)5]. This product is characterized by 1H, 13C, and 31P NMR and by X-ray diffraction as having one CH2 hydrogen (from a carbon located beta to Re) donating to the metal (agostic CH). This interaction occurs in preference to PNPR amide nitrogen pi-donation. DFT calculations confirm this agostic interaction, and show that the (PNPR)Re(H)2 fragment indeed reverses the greater stability of free olefin vs free carbene." @default.
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• W2016245628 date "2003-07-17" @default.
• W2016245628 modified "2023-10-16" @default.
• W2016245628 title "A π-Basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand" @default.
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• W2016245628 doi "https://doi.org/10.1021/ja035165x" @default.
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