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• W2016245835 abstract "Treatment of 6-dimethylamino-6-methylfulvene (1) with methyllithium gave the [C5H4CMe2NMe2]Li product (2) that was characterized by X-ray diffraction. Compound 2 features an oligomeric chain structure with the [C5H4CMe2NMe2] unit serving as a bridging ligand using its Cp anion moiety and the NMe2 donor functionality. Treatment of 2 with FeCl2 yielded the substituted ferrocene 3. The corresponding reaction of 2 with TiCl4(THF)2 gave the titanocene complex (C5H4CMe2NMe2)2TiCl2 (4) that exhibits an ordinary bent metallocene structure in the solid state without involvement of the pendant CMe2NMe2 donor ligands. In contrast, the titanium(III) complex (C5H4CMe2NMe2)2TiCl (5), obtained from the reaction of 2 with TiCl3(THF)3, has one of the two nitrogen donors strongly coordinated to the metal center. In the crystal, complex 5 thus attains a typical pseudotetrahedral Group 4 bent metallocene structure, as shown by an X-ray crystal structure analysis." @default.
• W2016245835 created "2016-06-24" @default.
• W2016245835 creator A5034807035 @default.
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• W2016245835 creator A5060827665 @default.
• W2016245835 date "2003-06-01" @default.
• W2016245835 modified "2023-09-23" @default.
• W2016245835 title "Synthesis and structural features of [(C5H4CMe2NMe2)2TiCl], a bis(cyclopentadienyl)Ti(III) complex with internal dimethylamino coordination" @default.
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• W2016245835 doi "https://doi.org/10.1016/s0022-328x(03)00221-3" @default.
• W2016245835 hasPublicationYear "2003" @default.
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