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• W2016259557 abstract "The crystallization of a glass with a composition Y35Si45Al20O83N17 expressed in equivalent %, which corresponds to a normalized composition Y0.28Si0.27Al0.16ON0.13, has been studied using an ultrasonic technique. The results were compared with those obtained by more classical techniques such as high temperature X-ray diffraction or differential thermal analysis. The analysis of the data was made within the frame of the general theory of transformation kinetics classically used for the interpretation of differential thermal analysis and differential scanning calorimetry experiments. The structure was studied by transmission electron microscopy at different stages of the glass to glass-ceramic transformation. The devitrification was shown to develop by homogeneous nucleation in the bulk and crystal growth was controlled by diffusion. The optimum nucleation temperature was determined to be 960°C and an activation energy for crystal growth rate found equal to 1025 ± 20 kJ mol−1." @default.
• W2016259557 created "2016-06-24" @default.
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• W2016259557 date "1997-04-01" @default.
• W2016259557 modified "2023-10-01" @default.
• W2016259557 title "Yttrium sialon glasses: Nucleation and crystallization of Y35Si45Al20O83N17" @default.
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• W2016259557 doi "https://doi.org/10.1016/s0022-3093(96)00624-2" @default.
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