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- W2016261770 abstract "The new metallacycle [PtIMe(CH2)4(dppm)], which contains both methylplatinum and platinacyclopentane groups, has been characterized by multinuclear NMR methods. It exists in solution as an equilibrium mixture of the two possible isomers having the fac-[PtC3] stereochemistry. The chelating (CH2)4 ligand is shown to exert a significantly higher trans-influence than the methyl ligand. Molecular mechanics calculations predict a slight preference for the less symmetrical isomer [Me and one CH2 group trans to dppm] over the more symmetrical isomer [two CH2 groups trans to dppm], in agreement with the experimental observations." @default.
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- W2016261770 date "1991-07-01" @default.
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- W2016261770 title "The synthesis and characterization of a platina(IV)cyclopentane complex" @default.
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- W2016261770 doi "https://doi.org/10.1016/0022-328x(91)86089-9" @default.
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