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• W2016276071 abstract "A kinetic model of infrared laser-induced fluorescence experiments has been used to simulate quenching coefficients between 300 and 2400 K for the vibrational relaxation of HF(v1) and DF(v1) by HF(v2=0) and DF(v2=0). This rotational nonequilibrium model is based on the predicted energy-transfer mechanisms in hydrogen–fluoride and deuterium–fluoride systems reported earlier by Wilkins. The deactivation rates for the V→R processes for HF(v1)+HF(v2=0) and their isotopic analogs are predicted to scale as vn with n varying from 2.3 to 1.6 as v varies from 2 to 6. These quenching coefficients for V→R processes from the upper vibrational levels are predicted to have a temperature dependence very similar to that for V→R relaxation from the v=1 level. The results are discussed in relation to V→V energy transfer and V→R intramolecular energy conversion." @default.
• W2016276071 created "2016-06-24" @default.
• W2016276071 creator A5041081551 @default.
• W2016276071 creator A5070958572 @default.
• W2016276071 date "1980-10-01" @default.
• W2016276071 modified "2023-09-27" @default.
• W2016276071 title "Temperature dependence of vibrational relaxation from the upper vibrational levels of HF and DF" @default.
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• W2016276071 doi "https://doi.org/10.1063/1.440559" @default.
• W2016276071 hasPublicationYear "1980" @default.
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