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- W2016287276 abstract "The synthesis of a new silylating reagent, tert.-butylpentafluorophenylmethylchlorosilane (tert.-buflophemesyl chloride) is described. The reagent forms volatile derivatives of alcohols, phenols, carboxylic acids, thiols and amines which are suitable for gas chromatography with electron-capture detection. The tert.-buflophemesyl derivatives are many-fold more stable towards hydrolysis than the flophemesyl derivatives to conditions such as partitioning between organic solvents and acid or base, thin-layer chromatography and column chromatography. The mass spectra of the derivatives show characteristics of both the flophemesyl and tert.-butyldimethylsilyl derivatives and are suitable for compound identification." @default.
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- W2016287276 date "1980-01-01" @default.
- W2016287276 modified "2023-09-26" @default.
- W2016287276 title "tert.-butylpentafluorophenylmethylchlorosilane as a reagent for the formation of hydrolytically stable alkylsilyl derivatives with electron-capturing properties" @default.
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- W2016287276 doi "https://doi.org/10.1016/s0021-9673(00)80465-3" @default.
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