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- W2016290434 abstract "The free energy $ensuremath{Delta}F$ due to the interaction through the crystal phonon field of two identical atoms adsorbed on a (100) surface of a simple cubic monatomic lattice is studied within the framework of the Montroll-Potts model. The zero-point energy of interaction, $ensuremath{Delta}{E}_{0}$, is found analytically in the limit of large separation distances, and numerical results are presented for small separation distances. The leading temperature-dependent terms in the expansion of $ensuremath{Delta}F$ are given in closed form in both the low- and high-temperature limits. The results are given as a function of the mass and separation distance of the adsorbed atoms and as a function of the force constant binding the adsorbed atoms to the surface. For all values of the model parameters, it is found that the free energy decreases with the separation distance. Thus, two adatoms on a surface are attracted toward each other." @default.
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- W2016290434 date "1973-05-15" @default.
- W2016290434 modified "2023-09-24" @default.
- W2016290434 title "Phonon Contribution to the Free Energy of Interacting Adatom Pairs" @default.
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- W2016290434 doi "https://doi.org/10.1103/physrevb.7.4643" @default.
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