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- W2016293191 abstract "The syntheses of cationic ruthenium(II) allenylidene complexes [(1a−e)PF6] of the type [CpRu(CCCR2)(PPh3)2]PF6 (1a, R2C: = cycloheptatrienylidene; 1b, R2C: = 2,7-dimethyl-4,5-benzocycloheptatrienylidene; 1c, R2C: = 2,7-diphenyl-4,5-benzocycloheptatrienylidene; 1d, R2C: = dibenzo[a,e]cycloheptatrienylidene; 1e, R2C: = 4,5-dihydrodibenzo[a,e]cycloheptatrienylidene) are reported. In the series 1a−e, the decreasing ability of R2C: to stabilize a positive charge results in a tuning of the electronic and optical properties by changing the relative contributions of the two canonical forms [Ru+]CCCR2 (A) and [Ru]C⋮CCR2+ (B), which is studied particularly by NMR and UV/visible spectroscopy. The first molecular hyperpolarizabilitiy β of (1b)PF6 has been determined by hyper Raleigh scattering. The X-ray crystal structures of (1b)PF6, (1d)PF6·CH2Cl2, and the acetylide complex CpRu(C⋮C−C7H7-2,4,6)(PPh3)2 are presented." @default.
- W2016293191 created "2016-06-24" @default.
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- W2016293191 date "1997-04-01" @default.
- W2016293191 modified "2023-09-25" @default.
- W2016293191 title "Ruthenium(II) Complexes with (2,4,6-Cycloheptatrien-1-ylidene)ethenylidene Ligands: Strongly Polarized Allenylidene Complexes" @default.
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- W2016293191 doi "https://doi.org/10.1021/om9610556" @default.
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