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- W2016295947 abstract "Methyltriazene and the O6 oxygen of guanine are believed to undergo a bimolecular nucleophilic substitution (S N 2) reaction to form methylguanine, which is proposed to be responsible for the cytotoxic properties of triazene-containing anti-neoplastic agents, such as Dacarbazine. To better understand the proposed mechanism of triazene-containing anti-neoplastic agents, a series of ab initio studies investigating the S N 2 reaction between methyltriazenes and halide ions were undertaken. The results of our investigation of the S N 2 reaction between 1,3,3-trimethyltriazene and the halide ions are presented here.Key words: triazene, trimethyltriazene, Dacarbazine, Temozolomide, bimolecular nucleophilic substitution reaction." @default.
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- W2016295947 date "2007-11-01" @default.
- W2016295947 modified "2023-09-30" @default.
- W2016295947 title "An exploratory ab initio study of the S<sub>N</sub>2 reaction of 1,3,3-trimethyltriazene with halide ions" @default.
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- W2016295947 doi "https://doi.org/10.1139/v07-110" @default.
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