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• W2016305002 abstract "Reactivities of four biomass samples were investigated in four combustion atmospheres using non-isothermal thermogravimetric analysis (TGA) under two heating rates. The chosen combustion atmospheres reflect carbon capture and storage (CCS) applications and include O2 and CO2-enrichment. Application of the Coats–Redfern method assessed changes in reactivity. Reactivity varied due to heating rate: the reactivity of char oxidation was lower at higher heating rates while devolatilisation reactions were less affected. In general, and particularly at the higher heating rate, increasing [O2] increased combustion reactivity. A lesser effect was observed when substituting N2 for CO2 as the comburent; in unenriched conditions this tended to reduce char oxidation reactivity while in O2-enriched conditions the reactivity marginally increased. Combustion in a typical, dry oxyfuel environment (30% O2, 70% CO2) was more reactive than in air in TGA experiments. These biomass results should interest researchers seeking to understand phenomena occurring in larger scale CCS-relevant experiments." @default.
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• W2016305002 date "2014-10-01" @default.
• W2016305002 modified "2023-09-25" @default.
• W2016305002 title "Reactivity during bench-scale combustion of biomass fuels for carbon capture and storage applications" @default.
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• W2016305002 doi "https://doi.org/10.1016/j.fuel.2014.05.050" @default.
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