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- W2016334198 abstract "The NMR proton chemical shifts of the CH2 group in phenyl phenacyl sulphones (β-keto sulphones)p-X-C6H4SO2CH2COC6H4-Y-p, measured in (CD3)2 are used to study transmission of the substituent effect through SO2 and CO groups. Contrary to the estimation of this effect from CH2-acidities [ρ(SO2) < ρ(CO)]4 the results were that ρ(SO2) > ρ(CO), and it was shown that application of σp+ gives a significantly better correlation than that with σp. These findings have been interpreted on the basis of structural data." @default.
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- W2016334198 date "1990-01-01" @default.
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- W2016334198 title "1H NMR study of the substituent transmission effects through SO2and CO groups in p,p′-disubstituted derivatives of phenyl phenacyl sulphones (β-keto sulphones)" @default.
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- W2016334198 doi "https://doi.org/10.1039/p29900000845" @default.
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