FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2016338082> ?p ?o ?g. }

• W2016338082 endingPage "16371" @default.
• W2016338082 startingPage "16363" @default.
• W2016338082 abstract "The photochemical production and chemical reactivity of a new coordinatively unsaturated rhodium monocarbonyl species on the surface of dealuminated zeolite Y over a temperature range of 300-420 K and a pressure range from 10(-5) to 20 Torr has been studied. Using high vacuum techniques and transmission infrared spectroscopy, ultraviolet irradiation (350 +/- 50 nm) of supported Rh(CO)(2) surface species led to the production of stable, but reactive, =Rh(CO) surface species, characterized by an infrared band at 2023 cm(-1). The coordinatively unsaturated =Rh(CO) species convert to less reactive and coordinatively saturated Rh(CO) by thermal treatment above 370 K. The Rh(CO) species were characterized by an infrared band at 2013 cm(-1). An explanation of the mode of bonding of the rhodium monocarbonyl species to the zeolite surface is provided. Coordinatively unsaturated =Rh(CO) species captured N(2), H(2), and O(2) gas molecules near room temperature to produce a variety of mixed ligand rhodium surface complexes of the form Rh(CO)(N(2)), Rh(CO)(H(2)), Rh(CO)(H)(2), Rh(CO)(H), Rh(CO)(O), and Rh(O). Infrared band assignments for the new species are provided. The work provides new insight into the photochemical behavior of Rh(CO)(2) species supported on high-area zeolite materials and may improve our understanding of the role of active rhodium monocarbonyl species in the development of heterogeneous photocatalysts." @default.
• W2016338082 created "2016-06-24" @default.
• W2016338082 creator A5080662928 @default.
• W2016338082 creator A5088155251 @default.
• W2016338082 date "2005-08-10" @default.
• W2016338082 modified "2023-09-25" @default.
• W2016338082 title "Surface Photochemistry of Rh(CO)₂ on Zeolite YProduction of a Stable Coordinatively Unsaturated Rhodium Monocarbonyl Surface Species at Room Temperature" @default.
• W2016338082 cites W1968515576 @default.
• W2016338082 cites W1969958105 @default.
• W2016338082 cites W1971342692 @default.
• W2016338082 cites W1973859129 @default.
• W2016338082 cites W1975259412 @default.
• W2016338082 cites W1977216259 @default.
• W2016338082 cites W1985600271 @default.
• W2016338082 cites W1985750908 @default.
• W2016338082 cites W1989431920 @default.
• W2016338082 cites W1990398853 @default.
• W2016338082 cites W1990850523 @default.
• W2016338082 cites W1993499217 @default.
• W2016338082 cites W1996035200 @default.
• W2016338082 cites W1996895112 @default.
• W2016338082 cites W1998446341 @default.
• W2016338082 cites W2003474605 @default.
• W2016338082 cites W2003691751 @default.
• W2016338082 cites W2004560204 @default.
• W2016338082 cites W2004687703 @default.
• W2016338082 cites W2009618648 @default.
• W2016338082 cites W2009762264 @default.
• W2016338082 cites W2010870113 @default.
• W2016338082 cites W2016272611 @default.
• W2016338082 cites W2024270383 @default.
• W2016338082 cites W2032061616 @default.
• W2016338082 cites W2032683210 @default.
• W2016338082 cites W2044071493 @default.
• W2016338082 cites W2052068039 @default.
• W2016338082 cites W2052411917 @default.
• W2016338082 cites W2053843228 @default.
• W2016338082 cites W2072783917 @default.
• W2016338082 cites W2081053291 @default.
• W2016338082 cites W2081822605 @default.
• W2016338082 cites W2083558783 @default.
• W2016338082 cites W2087106488 @default.
• W2016338082 cites W2091292786 @default.
• W2016338082 cites W2094139967 @default.
• W2016338082 cites W2168582519 @default.
• W2016338082 cites W2274998050 @default.
• W2016338082 cites W2527323647 @default.
• W2016338082 cites W2626015243 @default.
• W2016338082 cites W2949503369 @default.
• W2016338082 cites W310701048 @default.
• W2016338082 cites W4239049905 @default.
• W2016338082 doi "https://doi.org/10.1021/jp047673e" @default.
• W2016338082 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16853080" @default.
• W2016338082 hasPublicationYear "2005" @default.
• W2016338082 type Work @default.
• W2016338082 sameAs 2016338082 @default.
• W2016338082 citedByCount "6" @default.
• W2016338082 countsByYear W20163380822012 @default.
• W2016338082 countsByYear W20163380822014 @default.
• W2016338082 countsByYear W20163380822018 @default.
• W2016338082 crossrefType "journal-article" @default.
• W2016338082 hasAuthorship W2016338082A5080662928 @default.
• W2016338082 hasAuthorship W2016338082A5088155251 @default.
• W2016338082 hasConcept C116569031 @default.
• W2016338082 hasConcept C120665830 @default.
• W2016338082 hasConcept C121332964 @default.
• W2016338082 hasConcept C142724271 @default.
• W2016338082 hasConcept C153642686 @default.
• W2016338082 hasConcept C158355884 @default.
• W2016338082 hasConcept C161790260 @default.
• W2016338082 hasConcept C170493617 @default.
• W2016338082 hasConcept C178790620 @default.
• W2016338082 hasConcept C179104552 @default.
• W2016338082 hasConcept C185592680 @default.
• W2016338082 hasConcept C204787440 @default.
• W2016338082 hasConcept C2776910235 @default.
• W2016338082 hasConcept C2778077586 @default.
• W2016338082 hasConcept C32909587 @default.
• W2016338082 hasConcept C521398313 @default.
• W2016338082 hasConcept C55493867 @default.
• W2016338082 hasConcept C71924100 @default.
• W2016338082 hasConcept C75473681 @default.
• W2016338082 hasConceptScore W2016338082C116569031 @default.
• W2016338082 hasConceptScore W2016338082C120665830 @default.
• W2016338082 hasConceptScore W2016338082C121332964 @default.
• W2016338082 hasConceptScore W2016338082C142724271 @default.
• W2016338082 hasConceptScore W2016338082C153642686 @default.
• W2016338082 hasConceptScore W2016338082C158355884 @default.
• W2016338082 hasConceptScore W2016338082C161790260 @default.
• W2016338082 hasConceptScore W2016338082C170493617 @default.
• W2016338082 hasConceptScore W2016338082C178790620 @default.
• W2016338082 hasConceptScore W2016338082C179104552 @default.
• W2016338082 hasConceptScore W2016338082C185592680 @default.
• W2016338082 hasConceptScore W2016338082C204787440 @default.
• W2016338082 hasConceptScore W2016338082C2776910235 @default.
• W2016338082 hasConceptScore W2016338082C2778077586 @default.
• W2016338082 hasConceptScore W2016338082C32909587 @default.
• W2016338082 hasConceptScore W2016338082C521398313 @default.

• next