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- W2016343305 abstract "A green and low-cost adsorbent with both magnetic property and high adsorption capacity was prepared on the basis of nickel magnetic core with silica shell. The surface of the prepared Ni@SiO2 composite was not modified. The influence of different functional groups and different charged of the dyes on the adsorption process on the non functionalized Ni@SiO2 have been studied. The results indicated that synthesized adsorbent exhibited higher adsorption capacity for dyes with negative charge/hydroxyl groups as compared to dyes with positive charge/without hydroxyl groups due to the hydrogen bonding interaction and electrostatic interaction between the adsorbent and dyes. Adsorption kinetics and isotherms experiments were carried out and the results indicated that the adsorption process was fitted by pseudo second order kinetics and Freundlich model. The binding of these dyes with magnetic adsorbent surface mainly involves physical adsorption according to D–R model. Furthermore, the adsorption process is spontaneous and endothermic as studied from adsorption thermodynamics. The value of ΔH° and mean free energy further confirmed that physical adsorption is the major adsorption process. After regeneration, the adsorbent still shows high adsorption capacity even for 4 cycles of desorption–adsorption." @default.
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- W2016343305 date "2014-02-01" @default.
- W2016343305 modified "2023-10-02" @default.
- W2016343305 title "Enhanced adsorption of hydroxyl contained/anionic dyes on non functionalized Ni@SiO2 core–shell nanoparticles: Kinetic and thermodynamic profile" @default.
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- W2016343305 doi "https://doi.org/10.1016/j.apsusc.2013.11.136" @default.
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