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- W2016343331 abstract "Abstract p-Cresol, a model compound for an additive shown previously to be a potent photosensitizer of dehydrochlorination in poly(vinyl chloride) PVC, has been shown to sensitize dehydrochlorination in t-butyl chloride, a model for PVC. A quantitative study of the effect of chlorinated alkanes upon the fluorescence of p-cresol in solution reveals that quenching is due to charge transfer interactions, the halogenated compound acting as electron acceptor. Since the mono-halo compound t-butyl chloride does not quench p-cresol fluorescence, it was concluded that the photosensitization occurs via the triplet state of the p-cresol, and this view was confirmed by addition of triplet quenchers. A mechanism for the reaction is proposed, initial exciplex formation being followed by electron transfer." @default.
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- W2016343331 date "1978-01-01" @default.
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- W2016343331 title "The sensitized photodehydrochlorination of poly(vinyl chloride)—II. Model compound studies" @default.
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- W2016343331 doi "https://doi.org/10.1016/0014-3057(78)90013-7" @default.
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